In a closed insulated container,a liquid is stirred with a paddle to increase its temperature. Which of the following is correct?

The relation $q = -w$ is $NOT$ true for which of the following processes?

$A$ piston filled with $0.04 \ mol$ of an ideal gas expands reversibly from $50.0 \ mL$ to $375 \ mL$ at a constant temperature of $37.0 \ ^oC$. As it does so,it absorbs $208 \ J$ of heat. The values of $q$ and $w$ for the process will be
$(R = 8.314 \ J/mol \ K) \ (\ln 7.5 = 2.01)$

For the gaseous reaction $A_{(g)} + 3B_{(g)} \rightarrow 3C_{(g)} + 3D_{(g)}$,the value of $\Delta U = 17 \, Kcal$ at $27 \, ^oC$. Assuming $R = 2 \, cal \, K^{-1} \, mol^{-1}$,the value of $\Delta H$ for the above reaction will be ....... $Kcal$.

Which of the following processes exhibits a decrease in the internal energy of a system?

In ...... process,work is done at the expense of internal energy.